具有e指数内建电场的透射式GaAs光电阴极响应特性的理论分析

设计了具有e指数内建电场的透射式GaAs负电子亲和势阴极,利用数值计算方法研究了它的时间响应特性和量子效率特性。结果表明,当吸收区厚度L~0.2~1.5 μm时,阴极的响应时间和量子效率均随L的增大而增大;尤其当L~1.1 μm时响应时间达到10 ps,量子效率达到12.5%~20%,迄今为止,与其他GaAs光电阴极相比,在相同光谱响应条件下,该响应速度是最高的。另外,在不同L下,获得了平均时间衰减常数τ'的函数分布和能够获得最短响应时间的最优系数因子β分布,为新型高速响应GaAs光电阴极的时间响应和量子效率优化提供了必要的理论基础和数据支持。     

ICP法测定朱鹮羽毛中7种元素含量

用电感耦合等离子体(ICP)发射光谱法直接测定世界珍稀濒危鸟类——朱鹮羽毛中Cu,Zn,Mn,Ni,Cr,Fe,Mo七种元素的含量。结果表明,此方法简便,具有良好的精密度和准确性。     

Cobalt(II) and cobalt(III) coordination polymers constructed from flexible bis-imidazole and polycarboxyl co-ligands: syntheses,crystal structures and properties

Two metal coordination polymers, namely {[Co(1,3-BIP)(OBA)]·0.5H₂O}_n (SNUT-1) and [Co₂(µ-η¹:η¹-O₂)(1,3-BIP)₂(PMA)]_n (SNUT-2), where 1,3-BIP?=?1,3-bis(imidazol)propane, H₂OBA?=?4,4′-oxybis(benzoate) and H₄PMA?=?benzene-1,2,4,5-tetracarboxylic acid, were prepared by hydrothermal methods. Single-crystal X-ray analysis revealed that the structure of SNUT-1 consists of a 3D?→?3D twofold interpenetrating network that can be described as a 4-connected uninodal net with (6⁵·8) topology. The structure of SNUT-2 consists of a 3D framework which can be described as a (4,5)-connected binodal net with (4²·6³·8⁴·10) (3³·4²·5) topology. The gas adsorption properties of SNUT-1 and photocatalytic activity of SNUT-2 for the degradation of Rhodamine B have been explored.

     

基于凝聚函数的拟牛顿算法求解绝对值方程

绝对值方程Ax-|x|=b是一个不可微的NP-hard问题.在假设矩阵A的奇异值大于1(这里矩阵A的奇异值定义为矩阵ATA特征值的非负平方根)时,给出了求解绝对值方程一个新的光滑化算法.通过引入一种凝聚函数对绝对值方程进行光滑化处理,得到一个非线性方程组;再引入适当的目标函数,进而把绝对值方程化为无约束优化问题,然后利用拟牛顿算法对其进行求解.数值实验结果表明了该方法的正确性和有效性.     

用同步辐射X射线衍射技术分析GaN/Si外延膜的结构与应变

选用有AlN和AlGaN缓冲层的GaN/Si作为测试样品,采用同步辐射X射线衍射(SRXRD)技术对样品外延膜(GaN)的几何结构、晶格常量及其应变进行了分析.结果表明,同步辐射X射线衍射实验可以作为一种有效的技术手段,测试固体结构及应变.     

Simulation analysis of a novel fully depleted SOI MOSFET: Electrical and thermal performance improvement through trapezoidally doped channel and silicon–nitride buried insulator

In this paper, we present a novel nano-scale fully depleted silicon-on-insulator metal-oxide semiconductor field-effect transistor (SOI MOSFET). On-state current increment, leakage current decrement, and self-heating effect improvement are pursued in our proposed structure. The structure makes use of a buried insulator layer which consists of two materials to reduce the self-heating effect. On the other hand, to modify the sub- and super-threshold drain current, vertical trapezoidal doping distribution and additional side gate technique are employed. Our novel transistor is named dual material buried insulator vertical trapezoidal doping SOI MOSFET (DV-SOI MOSFET). We investigate the electrical performance and thermal behavior of the DV-SOI MOSFET using a commercial device simulator. We demonstrate that the proposed structure increases on–off current ratio by orders of magnitude and considerably improves self-heating effect in comparison with the conventional uniform doping fully depleted silicon-on-insulator MOSFET (C-SOI) which uses side gate for better electrical performance.     

Concise enantiodivergent synthesis of (+)- and (−)-trans-quercus lactones

A concise enantiodivergent total synthesis of (+)- and (−)-quercus lactones from the known tricyclic lactone (+)-1 as a single chiral template was achieved using the diastereoselective nucleophilic addition of organometallic reagents as the key step.     

海洋混合悬浮颗粒对蓝绿激光的散射特性研究

激光在水下的传输很大程度上会受到海水中悬浮颗粒物的影响,而目前对于海洋中悬浮颗粒物光散射的理论研究大多是针对单一成分的悬浮粒子而进行的,但是在真实海洋中悬浮颗粒物都是以多种成分混合的颗粒群形式而存在的,因此研究真实海洋中混合悬浮颗粒物对蓝绿激光的散射特性具有重要意义。该研究选取了对蓝绿激光传输产生较大影响的浮游藻类植物、悬浮泥沙、碎屑、悬浮气泡和矿物质这五种常见的悬浮颗粒物作为研究对象,充分考虑真实海况中这五种悬浮颗粒物的不同混合情况,构建了海水中混合球形悬浮颗粒物对蓝绿激光的散射特性模型。数值计算了海水中五种物质混合的球形悬浮颗粒物对532 nm蓝绿激光的统计平均光散射参量和平均散射相函数,分析不同混合悬浮颗粒物的混合比对平均散射、吸收和消光系数以及单次反照率随着粒子有效半径和粒子数浓度变化的影响,同时分析了不同粒子尺寸下的不同混合比对混合悬浮颗粒物的平均散射相函数随着角度变化的影响。数值结果表明,当悬浮泥沙在整个混合模型中占比越大时,平均散射系数越大,而当悬浮藻类粒子在整个混合模型中占比增大时,平均吸收系数增大,由此可知海洋中对光造成主要影响的五种常见悬浮颗粒物中,悬浮泥沙对光散射作用影响最大,悬浮藻类粒子对光吸收作用影响最大。随着悬浮颗粒物浓度的增大,混合粒子的单次反照率保持不变,由此可知混合悬浮颗粒物的平均光散射参量随着粒子浓度的增长速率是一致的。海洋中混合悬浮颗粒物的平均散射相函数随着粒子的有效半径的增大而增大,散射作用最大的混合比下的悬浮颗粒物其平均散射相函数最大,悬浮颗粒物的前向散射较强。该工作对蓝绿激光在海水中传输、信道建模,水下无线光通信的研究以及激光探测都具有重要的理论指导意义。     

Two-phase electrocatalysis by aqueous colloids

In this work, the combination of the advantages of two-phase catalysis, electrocatalysis and colloid catalysis is presented. It is shown that palladium or gold colloids prepared by citrate reduction can be charged negatively in a heterogeneous two-phase reaction and subsequently used as aqueous catalysts for dehalogenation reactions. This can be regarded as a new type of electrocatalysis.